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ChemInform Abstract: Iodine-Catalyzed Highly Effective Pictet—Spengler Condensation: An Efficient Synthesis of Tetrahydro-β-carbolines.

✍ Scribed by Dipak Prajapati; Mukut Gohain

Publisher
John Wiley and Sons
Year
2009
Weight
22 KB
Volume
40
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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## Abstract Under catalysis of diphenylphosphate, tryptamine undergoes a two‐step one‐pot reaction with 1,3‐dicarbonyl compounds and α,β‐unsaturated aldehydes to give the title compounds bearing two chiral centers as almost single diastereomers (< 95% d.e.).