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ChemInform Abstract: Iodine-Catalyzed Formation of Aza-Dienes: A Novel Synthesis of Angularly Fused Hexahydropyrano- and Furo[3,2-c]quinoline Derivatives.

✍ Scribed by B. V. Subba Reddy; Harish Grewal

Book ID
102064827
Publisher
John Wiley and Sons
Year
2011
Weight
30 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

The reaction provides an efficient access to quinoline derivatives of potential biological relevance.

πŸ“œ SIMILAR VOLUMES

Iodine-catalyzed formation of aza-dienes
Iodine-catalyzed formation of aza-dienes: a novel synthesis of angularly fused hexahydropyrano- and furo[3,2-c]quinoline derivatives
✍ B.V. Subba Reddy; Harish Grewal πŸ“‚ Article πŸ“… 2011 πŸ› Elsevier Science 🌐 French βš– 886 KB

In situ generated aza-diene, from N-[methyl-N-(trimethylsilyl)methyl]aniline in the presence of a catalytic amount of molecular iodine undergoes smooth [4+2] cycloaddition with electron-rich enol ethers, such as 3,4-dihydro-2H-pyran and 2,3-dihydrofuran under mild and neutral conditions to afford th