ChemInform Abstract: Intramolecular Iodoetherification of Ene or Diene Ketals: Facile Synthesis of Spiroketals.
β Scribed by Hiromichi Fujioka; Kenji Nakahara; Hideki Hirose; Kie Hirano; Tomohiro Oki; Yasuyuki Kita
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 30 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
Chiral spiroketals (II), (VI) and (IX) are synthesized based on remote asymmetric induction.
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## Abstract Treatment of esters (I) and (III) with zinc in acetic acid allows formation of title compounds (II) and (IV) under environmentally friendly mild conditions.