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ChemInform Abstract: Intramolecular Electron Transfer Between Terminal 1,4-Dimethoxybenzene Units in Radical Cations with a [2.2](1,4)Naphthalenophane, [2.2](1,4)Anthracenophane, and Pentacene Skeleton.

✍ Scribed by A. R. WARTINI; H. A. STAAB; F. A. NEUGEBAUER

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199835033

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✦ Synopsis

1998 structure structure (organic substances) K 9000 35 -033 Intramolecular Electron Transfer Between Terminal 1,4-Dimethoxybenzene Units in Radical Cations with a 2.2Naphthalenophane, 2.2Anthracenophane, and Pentacene Skeleton. -Whereas the syn-and anti-conformer of radical cation (I) show delocalization of the unpaired electron over the whole molecule, benzoanellation in anti-anthracenophane (II) results in a localized radical cation, and the terminal 1,4-dimethoxybenzene units in (III) are integral parts of a strongly delocalized system. -(WARTINI,

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