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ChemInform Abstract: Intramolecular Cyclization of C2 Symmetric and meso-Iodo Amino Alcohols: A Synthetic Approach to Azasugars.

✍ Scribed by S. H. KANG; D. H. RYU

Publisher: John Wiley and Sons
Year: 2010
Weight: 32 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199717210

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✦ Synopsis

Intramolecular Cyclization of C2 Symmetric and meso-Iodo Amino Alcohols: A Synthetic Approach to Azasugars.

-Hydrolysis of meso-(I) followed by Boc-protection provides a mixture of 4 azasugars (III)-(VI). They can be elaborated into a number of derivatives. Furthermore, acidic cleavage of (I) followed by Boc-protection leads to the fused tetrahydrofuran (XIII), whose skeleton is structurally related to the clinically useful angina pectoris and heart failure agent KF-14124. -(KANG, S. H.; RYU, D. H.;

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