## Stereochemistry of Lewis Acid and Fluoride Promoted Intramolecular Cyclization of Ξ²-(Alkoxycarbonyl)allylsilane with Enones. Synthesis of Bicyclo(4.3.0)nonanes. -The title reaction is found to yield cyclohexanes and/or bicyclo(4.3.0) nonanes, a common unit present in terpenoid natural products.
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ChemInform Abstract: Intramolecular Cyclization of 2-(Alkoxycarbonyl)allylsilanes with Ynones. Nucleophilic and Electrophilic Aspects of the 2-(Alkoxycarbonyl)allylsilane Moiety.
β Scribed by Chiaki Kuroda; Yoshihiro Kimura; Hiroyuki Nogami
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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