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ChemInform Abstract: Intramolecular Aromatic Carbenoid Insertion of Biaryldiazoacetates for the Regioselective Synthesis of Fluorenes.

✍ Scribed by Jinho Kim; Youhwa Ohk; Sae Hume Park; Yousung Jung; Sukbok Chang

Publisher
John Wiley and Sons
Year
2011
Weight
60 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

Dirhodium acetates or copper triflate catalyze the highly regioisomeric formation of the fluorenes from appropriately substituted biaryldiazoacetates, whereas under thermal conditions a significantly reduced regioselectivity is observed.

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