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ChemInform Abstract: Intramolecular 1,4-Dipolar Cycloaddition Reaction of Thiazinium Betaines for the Construction of Aza-, Diaza-, and Polyaza- Heterocyclic Ring Systems.

โœ Scribed by A. PADWA; S. J. COATS; S. R. HARRING; L. HADJIARAPOGLOU; M. A. SEMONES


Book ID
112024030
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
26
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Stereochemistry. Pa
โœ I. N. N. NAMBOOTHIRI; A. HASSNER; H. E. GOTTLIEB ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 32 KB ๐Ÿ‘ 1 views

Strategy for the Construction of Functionalized Five-and Six-Membered Carbocycles. -Conjugate addition of the Grignard reagents (II) and (IV) to the nitro olefins (I) leads to the intermediate formation of nitronates, which are trapped as silyl nitronates and subsequently cyclized by intramolecular