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ChemInform Abstract: Insertion of N=N and O=O Bonds in Tin and Lead Allyl Bonds in Metallocene Reactions Catalyzed by Lithium Perchlorate.

✍ Scribed by Wojciech J. Kinart; Izabela Tylak; Cezary M. Kinart

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199920146

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✦ Synopsis

Insertion of N=N and O=O Bonds in Tin and Lead Allyl Bonds in Metallocene Reactions Catalyzed by Lithium Perchlorate.

-A new example of catalysis by lithium perchlorate of metallocene reactions with singlet oxygen and azodicarboxylate (III) is reported in which the insertion of N=N and O=O bonds in the Sn and Pb allyl bonds in (I) and (V) forming (II), (IV), or (VI), resp., is possible. -(KINART,

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