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ChemInform Abstract: In situ Manganese Dioxide Alcohol Oxidation—Wittig Reactions: Preparation of Bifunctional Dienyl Building Blocks.

✍ Scribed by Xudong Wei; Richard J. K. Taylor


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
31
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Manganese Dioxide C
✍ Leonie Blackburn; Xudong Wei; Richard J. K. Taylor 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

Manganese Dioxide Can Oxidize Unactivated Alcohols under in situ Oxidation-Wittig Conditions. -In the absence of Wittig reagent activated MnO 2 oxidizes primary alcohols to the corresponding aldehydes. However, low yields are observed (decanal 12%). -(BLACKBURN, LEONIE;