steps). The non-natural (R)-vesperal was also prepared from (S)-limonene. Scheme 2. Synthesis of vesperal (1): reagents: (a) (i) nBuLi, TMEDA; (ii) O 2 (iii) 25% Na 2 SO 3 aq. soln. (30%); (b) Ac 2 O, C 5 H 5 N (quant.); (c) MCPBA, NaHCO 3 , CH 2 Cl 2 (86%); (d) Ph 2 Se 2 , NaBH 4 , EtOH (70% of 7 a
β¦ LIBER β¦
ChemInform Abstract: Identification and Synthesis of Vesperal, the Female Sex Pheromone of the Longhorn Beetle Vesperus xatarti.
β Scribed by F.-D. BOYER; C. MALOSSE; P. ZAGATTI; J. EINHORN
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 36 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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