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ChemInform Abstract: Hydrosilanes Are not Always a Reducing Reagent: A Ruthenium-Catalyzed Introduction of Primary Alkyl Groups to Electron-Rich Aromatic Rings Using Esters as a Source of the Alkyl Groups.

✍ Scribed by Hideo Nagashima; Yuichi Kubo; Mitsunobu Kawamura; Takashi Nishikata; Yukihiro Motoyama


Publisher
John Wiley and Sons
Year
2012
Weight
45 KB
Volume
43
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

Although it is limited to electron‐rich aromatic compounds, the combination of a hydrosilane, an ester, and the ruthenium cluster provides a good method to introduce a primary alkyl group to the aromatic compound.