The hydrohalogenation reaction of 1,2-allenic sulfoxides 1 afforded 2-haloallyl sulfoxides 2 with yields ranging from 56 to 89%. The influence of the ratio of AlCl 3 and H 2 O on this reaction is discussed and the optimized ratio of allenic sulfoxides, AlCl 3 and H 2 O is 1:0.55:1. For the hydroiodi
β¦ LIBER β¦
ChemInform Abstract: Hydrohalogenation Reaction of 1,2-Allenic Sulfoxides with AlX3 and H2O: Efficient Synthesis of 2-Haloallyl Sulfoxides.
β Scribed by Shengming Ma; Qi Wei
- Publisher
- John Wiley and Sons
- Year
- 2001
- Weight
- 33 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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