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ChemInform Abstract: Hydrogenation and Conformational Analysis of (1R,2R,6S)-3-Methyl-6-(1-methylethenyl)cyclohex-3-ene-1,2-diol.

✍ Scribed by O. V. Ardashov; A. M. Genaev; I. V. Il'ina; D. V. Korchagina; K. P. Volcho; N. F. Salakhutdinov

Publisher: John Wiley and Sons
Year: 2011
Weight: 22 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201123172

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✦ Synopsis

Abstract

Nickel hydridoborate, generated in situ from NiCl~2~ and NaBH~4~, selectively reduces the exocyclic double bond in title compound (I) furnishing compound (II) in good yield.

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ChemInform Abstract: Efficient Synthesis

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ChemInform Abstract: Diastereoselective

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Synthesis and Unusual Hydrolysis Product

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