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ChemInform Abstract: Hydrogen-Activated Benzylidynetricobalt Nonacarbonyl: Carbonylative Cyclization of Enynes in Synthesis Gas Without Reducing Substrates and Products.

✍ Scribed by Takumichi Sugihara; Akihito Wakabayashi; Mugio Nishizawa; Shinobu Honzawa


Book ID
102068657
Publisher
John Wiley and Sons
Year
2011
Weight
37 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

The hydrogen present in the synthesis gas is able to activate metal complexes which in turn catalyze the carbonylative cyclization of enynes to afford cyclopentenones.