ChemInform Abstract: Hydrido Complexes of Palladium
β Scribed by V. V. GRUSHIN
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 23 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
## 5 . The totally symmetric MH stretches (A 1g ), which are of lower intensity, are shifted by about 50 cm -1 to higher wavenumbers compared with the asymmetric stretches. The results of a group theoretical treatment of the respective site group and unit-cell group modes are given.
The five-coordinate compound [RuHCl(CO)(PiPr 2 Ph) 2 ] (1), [RuHCl 2 (CO)(PiPr 2 Ph) 2 ] -contains the chloro ligands in cis and the phosphanes in trans disposition. The Ru=CH 2 bond which was prepared from RuCl 3 β’ 3 H 2 O and PiPr 2 Ph in methanol in the presence of NEt 3 , reacts with CO and wit