ChemInform Abstract: Hydration of Acetylenic Esters: Synthesis of β-Keto-Esters.
✍ Scribed by M. G. CONSTANTINO; I. CARVALHO; G. V. J. DA SILVA; F. C. ARCHANJO
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 37 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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Transesterifications of methyl β-keto carboxylates catalyzed by DMAP with various high boiling alcohols can be accomplished in refluxing cyclohexane in a Dean-Stark trap. The MeOH formed is removed completely from the reaction mix-