✦ LIBER ✦
ChemInform Abstract: How Does Organic Structure Determine Organic Reactivity? Nucleophilic Substitution and Alkene-Forming Elimination Reactions of α- Carbonyl and α-Thiocarbonyl Substituted Benzyl Derivatives.
✍ Scribed by J. P. RICHARD; S.-S. LIN; J. M. BUCCIGROSS; T. L. AMYES
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
How Does Organic Structure Determine Organic Reactivity? Nucleophilic Substitution and Alkene-Forming Elimination Reactions of α-Carbonyl and α-Thiocarbonyl Substituted Benzyl Derivatives.
-Experimental and computational studies are reported in order to characterize the effect of α-(N,N-dimethylcarbamoyl) and α-(N,N-dimethylthiocarbamoyl) substituents on the rate constants of solvolysis and deprotonation. The results are discussed in terms of the relative thermodynamic stabilities of the neutral products. -(RICHARD,