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ChemInform Abstract: Hosomi—Sakurai Reactions of Silacyclohexenes.

✍ Scribed by Nicholas J. Hughes; Robert D. C. Pullin; Mahesh J. Sanganee; Jonathan D. Sellars; Patrick G. Steel; Michael J. Turner

Publisher
John Wiley and Sons
Year
2008
Weight
48 KB
Volume
39
Category
Article
ISSN
0931-7597

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Asymmetric Hosomi-Sakurai Reaction of Allylsilanes Containing Arabinose-Derived Alcohols as Chiral Auxiliaries. -The title investigation is presented with a view to the synthetic value of chiral homoallylic alcohols. The e.e. of the reactions of enantiomerically pure allylsilanes (I) with aldehydes