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ChemInform Abstract: Homologation of Polyamines in the Synthesis of Lipo-Spermine Conjugates and Related Lipoplexes.

✍ Scribed by A. J. GEALL; I. S. BLAGBROUGH

Publisher: John Wiley and Sons
Year: 2010
Weight: 32 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199816266

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✦ Synopsis

Homologation of Polyamines in the Synthesis of Lipo-Spermine

Conjugates and Related Lipoplexes.

-In continuation of efforts on the synthesis of polyamine amides useful in gene delivery as synthetic vectors or mimics of polycationic histones, the amides ( IV) and (VIII) are prepared. The synthesis of (VIII) involves a homologation strategy via reductive amination of the aldehyde (V) with the selectively protected spermine (I). -(GEALL, A.

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