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ChemInform Abstract: Homologation of Methyl 2-Azido- and 2-Acetamido-3,4-di-O-benzyl-2-deoxy-D-hexopyranosides with Allyloxymethylmagnesium Chloride.

โœ Scribed by Barbara Grzeszczyk; Aleksander Zamojski


Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
32
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Synthesis and Glyco
โœ G. YANG; F. KONG ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 39 KB ๐Ÿ‘ 1 views

Synthesis and Glycosidic Coupling Reaction of Substituted 2,6-Dioxabicyclo[3.1.1]heptanes: 1,3-Anhydro-2-azido-4,6-di-O-benzyl-2deoxy-ฮฒ-D-mannopyranose. -The title sugar (VII) is synthesized via the key intermediate (VI) starting from glucopyranoside (I). Anhydrosugar (VII) is quite reactive: ring-