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ChemInform Abstract: HIO3 and I2O5: Mild and Selective Alternative Reagents to IBX for the Dehydrogenation of Aldehydes and Ketones.

✍ Scribed by K. C. Nicolaou; Tamsyn Montagnon; Phil S. Baran

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
33
Category
Article
ISSN
0931-7597

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Abstract

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HIO3 and I2O5: Mild and Selective Altern
HIO3 and I2O5: Mild and Selective Alternative Reagents to IBX for the Dehydrogenation of Aldehydes and Ketones
✍ K. C. Nicolaou; Tamsyn Montagnon; Phil S. Baran 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 32 KB

wurden die Komplexe HIO 3 •DMSO und I 2 O 5 •DMSO als neue Reagentien für die Dehydrierung von Ketonen und Aldehyden zu den entsprechenden Enonen und Enalen beschrieben. Die Reagentien wurden durch einstündiges Erhitzen von 1 m DMSO-Lösungen von Iodsäure (HIO 3 ) oder Iod(v)-oxid (I 2 O 5 ) auf 80 8