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ChemInform Abstract: Highly Stereospecific Conversion of C-Centrochirality of a 3,4-Dihydro-2H-1,1′-binaphthalen-1-ol into Axial Chirality of a 3,4-Dihydro-1,1′-binaphthalene.

✍ Scribed by Tetsutaro Hattori; Masamitsu Date; Kenta Sakurai; Naoya Morohashi; Hiroshi Kosugi; Sotaro Miyano

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
33
Category
Article
ISSN
0931-7597

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Abstract

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## Abstract On irradiation (__λ__=350 nm) in the presence of 1,1‐dimethoxyethene, naphthalene‐1,2‐dionemonoacetals **1** regioselectively afford 1,1,4,4‐tetramethoxycyclobuta[__a__]naphthalen‐3‐ones **3**. Sequential deprotection of these bis‐acetals first lead to 1,1‐dimethoxycyclobuta[__a__]napht