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ChemInform Abstract: Highly Stereoselective 1,4-Asymmetric Reactions of 2-(Arylsulfinyl)benzaldehydes and 2-(Arylsulfinyl)phenyl Ketones.

✍ Scribed by Shuichi Nakamura; Masahiro Oda; Hiroki Yasuda; Takeshi Toru

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
33
Category
Article
ISSN
0931-7597

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Highly Diastereoselective Intermolecular Ξ²-Addition of Alkyl Radicals to Chiral 2-(Arylsulfinyl)-2-cycloalkenones. -The reaction of cycloalkenones having chiral bulky arylsulfinyl groups proceeds with excellent diastereoselectivity. In the presence of the Lewis acids EtAlCl 2 and TiCl 2 (OiPr) 2 re