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ChemInform Abstract: Highly Stereocontrolled Synthesis of a Novel Tribactam by Reaction of an Ester Enolate with a N-Trimethylsilylimine.

✍ Scribed by R. CAMERINI; M. PANUNZIO; G. BONANOMI; D. DONATI; A. PERBONI

Book ID: 112035393
Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 27
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199631213

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Enolates with Imines. -Based on a ternary complex reagent, which comprises three components, a chiral ether ligand, an achiral lithium amide and (I), the asymmetric addition of (I) to an imine (II) leads to the β-lactams such as (III) and (V) in high enantiomeric excess. The enantioselectivity and