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ChemInform Abstract: Highly Regio- and Stereoselective Cycloreductions of 1,6- and 1,7-Enynes Activated with a Carbonyl Functionality.

โœ Scribed by Chang Ho Oh; Hyung Hoon Jung; Joo Sung Kim; Seung Woo Cho

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
31
Category
Article
ISSN
0931-7597

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The cyclization of enynes or halodienes has been widely utilized in the synthesis of structurally complex natural and synthetic products. [1] Various 1,6-and 1,7-enynes, aided by suitable palladium catalysts, cycloisomerize to the corresponding dienes, [2] which could further serve as valuable water

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## Abstract Optimized conditions are developed which allow the preparation of the desired enynes with high or complete (E) selectivity in the absence of any ligand or additive.