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ChemInform Abstract: Highly Regio- and Enantioselective Catalytic Hydrogenation of Enamides in Conjugated Diene Systems: Synthesis and Application of γ,δ-Unsaturated Amino Acids.

✍ Scribed by M. J. BURK; J. G. ALLEN; W. F. KIESMAN

Publisher: John Wiley and Sons
Year: 2010
Weight: 35 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199824064

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✦ Synopsis

1998 aminocarboxylic acids

aminocarboxylic acids (hydrazinocarboxylic acids) and esters (acyclic compounds) P 0270

24 -064

Highly Regio-and Enantioselective Catalytic Hydrogenation of Enamides in Conjugated Diene Systems: Synthesis and Application of γ,δ-Unsaturated Amino Acids.

-An efficient method for the asymmetric hydrogenation of conjugated α,γ-dienamide esters, prepared by the Suzuki cross-coupling reaction and the Horner-Emmons olefination, resp., is presented, using Rh/Et-DuPHOS as the catalytic system. -(BURK, M.

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