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ChemInform Abstract: Highly Enantioselective Conjugate Additions of Phosphites to α,β-Unsaturated N-Acylpyrroles and Imines: A Practical Approach to Enantiomerically Enriched Amino Phosphonates.

✍ Scribed by Depeng Zhao; Yuan Wang; Lijuan Mao; Rui Wang

Publisher
John Wiley and Sons
Year
2010
Weight
60 KB
Volume
41
Category
Article
ISSN
0931-7597

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Abstract

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Highly Enantioselective Conjugate Additi
Highly Enantioselective Conjugate Additions of Phosphites to α,β-Unsaturated N-Acylpyrroles and Imines: A Practical Approach to Enantiomerically Enriched Amino Phosphonates
✍ Depeng Zhao; Yuan Wang; Lijuan Mao; Rui Wang 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 275 KB

## Abstract The first highly enantioselective phosphonylation of α,β‐unsaturated __N__‐acylpyrroles has been developed. Excellent yields (91–99 %) and enantioselectivities (up to >99 % enantiomeric excess (__ee__)) were observed for a broad spectrum of both phosphites and __N__‐acylpyrroles under m