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ChemInform Abstract: Highly Enantioselective and Regioselective Copper-Catalyzed 1,4 Addition of Grignard Reagents to Cyclic Enynones.

โœ Scribed by Matthieu Tissot; Alexandra Perrez Hernandez; Daniel Mueller; Marc Mauduit; Alexandre Alexakis


Publisher
John Wiley and Sons
Year
2011
Weight
51 KB
Volume
42
Category
Article
ISSN
0931-7597

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Enantioselective Copper-Catalyzed 1,4-Ad
โœ Maurus Spescha; Grety Rihs ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 693 KB

The enantioselective copper-catalyzed 1,4-addition of Grignard reagents to a$-unsaturated carbonyl compounds was studied with the following Cu' compounds as catalyst precursor and 1,2 : 5,6-di-0 -isopropylidene-3thio-a -o-glucofuranose (Hsiig) as chiral ligand: CuI, iodo[bis(dibutylsulfide)]copper(I