Enantioselective Borane Reduction of Ketones Catalyzed by Chiral Lanthanum Alkoxides. -The enantioselective reduction of simple unfunctionalized ketones (I) is achieved by borane in the presence of a preformed catalyst from (R)-binaphthol and lanthanum triisopropoxide. -(ZHANG,
✦ LIBER ✦
ChemInform Abstract: Highly Efficient Enantioselective Epoxidation of α,β-Enones Catalyzed by Cheap Chiral Lanthanum and Gadolinium Alkoxides.
✍ Scribed by Ruifang Chen; Changtao Qian; Johannes G. de Vries
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 37 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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