✦ LIBER ✦
ChemInform Abstract: Highly (E)-Selective BF3·Et2O-Promoted Allylboration of Chiral Nonracemic α-Substituted Allylboronates and Analysis of the Origin of Stereocontrol.
✍ Scribed by Ming Chen; William R. Roush
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 43 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
(E)‐δ‐Methyl‐substituted homoallylic alcohols (III) are prepared in high yields and excellent enantioselectivities from α‐methyl‐allylboronate, derived from pinanediol.