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ChemInform Abstract: Highly Diastereoselective Nucleophilic Addition of Organometallic Reagents to 2-Pyrrolidinyl Nitrones: A Semiempirical Approach.

✍ Scribed by Pedro Merino; Santiago Franco; Jose M. Gascon; Francisco L. Merchan; Tomas Tejero


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Diastereoselective
✍ G. POLI; E. MACCAGNI; L. MANZONI; T. PILATI; C. SCOLASTICO πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 30 KB πŸ‘ 1 views

Diastereoselective Addition of Metal-Coordinated and "Naked" Nucleophilic Reagents to Norephedrine Derived 2-Acyl-N-tosyl-oxazolidines. -Under chelating or non-coordinating conditions the addition of tris-s-butyl borohydrides to (I) can be directed with high selectivity. Under these conditions the