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ChemInform Abstract: Highly Diastereoselective Hetero-Diels—Alder Reactions of Alkenyldihydrooxazoles as an Approach to Novel Pyrimidine Derivatives.

✍ Scribed by M. C. ELLIOTT; E. KRUISWIJK

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
29
Category
Article
ISSN
0931-7597

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✍ R. BADORREY; C. CATIVIELA; M. D. DIAZ-DE-VILLEGAS; J. A. GALVEZ 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 2 views

Asymmetric Hetero Diels-Alder Reaction of N-Benzylimines Derived from ( R)-Glyceraldehyde: A New Approach to Homochiral Piperidine Building Blocks and Its Application to the Synthesis of (2R)-4-Oxopipecolic Acid. -The D-glyceraldehyde derived N-benzyl imine (I) undergoes a highly diastereoselective