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ChemInform Abstract: Highly Diastereoselective and Enantioselective Formal [4 + 1] Ylide Annulation for the Synthesis of Optically Active Dihydrofurans.

✍ Scribed by Jun-Cheng Zheng; Chun-Yin Zhu; Xiu-Li Sun; Yong Tang; Li-Xin Dai


Publisher
John Wiley and Sons
Year
2009
Weight
42 KB
Volume
40
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.


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## Abstract In the presence of Fe(Cl~4~tpp) and pyridine base, α‐ylidene‐β‐diketones and Ξ±,β‐unsaturated imines react with diazoacetates to provide the title heterocycles as single diastereomers.