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ChemInform Abstract: High-Pressure-Promoted Diels—Alder Reactions Between Cycloalkenones and 3-Methylsulfanylfuran and 3-Phenylsulfanylfuran.

✍ Scribed by H. Surya Prakash Rao; Rajappa Murali; Aldo Taticchi; Hans W. Scheeren

Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
33
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

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High-Pressure-Promoted Diels−Alder React
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3-Methylsulfanylfuran and 3-phenylsulfanylfuran were found to undergo facile, regioselective and stereoselective Diels-Alder (DA) cycloaddition to a variety of cycloalkenones under high pressure to give the corresponding ringannulated 7-oxabicyclo[2.2.

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The High Pressure Diels-Alder Reactions of Quinone-mono-ketals. -Simple quinone-mono-ketals react with nonactivated dienes at high pressure to yield the corresponding adducts. Treatment of these adducts with catalytic acid forms the aromatized products, i.e. the annulated benzenes or naphthalenes.