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ChemInform Abstract: High Diastereoselectivity in Claisen Rearrangement in a Sterically Congested Cyclopentane System. Total Synthesis of (.+-.)-β-Necrodol.

✍ Scribed by Susanta Samajdar; Anjan Ghatak; Shyamapada Banerjee; Subrata Ghosh

Publisher: John Wiley and Sons
Year: 2010
Weight: 33 KB
Volume: 32
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200133216

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Abstract

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✍ M. T. CRIMMINS; Z. WANG; L. A. MCKERLIE 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 41 KB

## Double Diastereoselection in Intramolecular Photocycloadditions: A Radical Rearrangement Approach to the Total Synthesis of the Spirovetivane Phytoalexin (±)-Lubiminol. -Key steps in the synthesis of the title compound (XIII) are a conjugate addition-cyclization reaction to prepare compound (I