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ChemInform Abstract: Hexahydro-closo-hexaborate as a Ligand in Coordination Compounds: Synthesis and Crystal Structure of (n-Bu4N)2 [Cd(η3-B6H6)2] ×2CH2Cl2.

✍ Scribed by T. SCHAPER; W. PREETZ


Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
29
Category
Article
ISSN
0931-7597

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[ReIII(thiourea-S)6]Cl3 · 4 H2O and [ReI
✍ Lucía Otero; Julio Benítez; Dinorah Gambino; Eduardo Kremer; Enrique J. Baran; A 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 111 KB

Capability of [Re III (tu-S) 6 ]Cl 3 , where tu = thiourea, as a precursor to other Re III complexes by ligand substitution in aqueous medium is studied. For the decomposition of [Re(tu-S) 6 ]Cl 3 , experiments suggest pseudo first order kinetics and observed rate constants vary from 1.3 ´10 ±2 to 9