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ChemInform Abstract: “Heteroglycals” as New Potential Glycosidase Inhibitors. Synthetic Approaches from D-Arabinose.

✍ Scribed by Arnaud Tatibouet; Patrick Rollin; Olivier R. Martin


Publisher
John Wiley and Sons
Year
2000
Weight
35 KB
Volume
31
Category
Article
ISSN
0931-7597

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ChemInform Abstract: A New Synthetic App
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The functionalized tricyclic framework (XI) of the diterpene forskolin is synthesized by an intramolecular Diels-Alder reaction of the dienyne (VII), which is obtained by stereoselective introduction of the C side chains at C-1 and C-2 of tri-O-acetyl-D-galactal (I) via C-Ferrier and Claisen-Ireland