ChemInform Abstract: Heterocyclizations of 1,4-Diazido-2,3-diarylthio-9,10-anthraquinones.
β Scribed by L. M. GORNOSTAEV; T. I. LAVRIKOVA; E. V. ARNOL'D
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Heterocyclizations of 1,4-Diazido-2,3-diarylthio-9,10-anthraquinones.
-Diazidoanthraquinones of type (II) undergo stepwise thermic cyclization. Under mild conditions, the phenothiazines (III) are obtained, whereas in refluxing toluene both azido groups participate in cyclizations to give oxazolo anellated systems (IV). -(GORNOSTAEV, L. M.; LAVRIKOVA, T. I.;
π SIMILAR VOLUMES
Photochemical and Thermal Rearrangements of 2-Arylamino-1-(4tert-butylphenoxy)-9,10-anthraquinones. -Irradiation of the title 2-arylaminoanthraquinones (III) proceeds by migration of the tert-butylphenyl group to the 9-carbonyl oxygen to furnish 1,10-anthraquinones [as hydrolysis products (IV)] or
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