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ChemInform Abstract: Hetero π Systems. Part 26. C3H4Si Species: Generation and Matrix-Spectroscopic Identification of Some Silacyclobutadiene Isomers.

✍ Scribed by G. MAIER; H. P. REISENAUER; J. JUNG; H. PACL; H. EGENOLF

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
29
Category
Article
ISSN
0931-7597

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C3H4Si Species: Generation and Matrix-Sp
C3H4Si Species: Generation and Matrix-Spectroscopic Identification of Some Silacyclobutadiene Isomers
✍ Günther Maier; Hans Peter Reisenauer; Jörg Jung; Harald Pacl; Heiko Egenolf 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 457 KB 👁 2 views

Flash pyrolyses of four suitable precursors -namely 1,1,1-composition (12, 13, 14, 17, and 18) were identified. Except ethynylsilaethene (18), all compounds observed are silylenes. trimethyl-2-propargyldisilane (32), its allenyl (34) and propynyl isomer (35), as well as 2-ethynyl-1,1,1,2-Their ident