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ChemInform Abstract: Hetero-Diels—Alder and Related Reactions

✍ Scribed by Takashi Ooi; Keiji Maruoka


Publisher
John Wiley and Sons
Year
2010
Weight
24 KB
Volume
31
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.


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Asymmetric Hetero-Diels-Alder Reactions with Heterocumulenes. -Chiral 2-alkenyloxazolines or thiazolines (I) and (IV) undergo hetero-Diels-Alder reaction with the ketene (II) or the isocyanate (VI) giving adducts with complete stereocontrol. In the case of oxazoline (I) a fast second addition yield