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ChemInform Abstract: Hemiaminals of Trifluoroacetaldehyde, as Trifluoromethylating Agents.

✍ Scribed by Clotilde Mispelaere; Nicolas Roques


Book ID
101884825
Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
30
Category
Article
ISSN
0931-7597

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Hemiaminals of trifluoroacetaldehyde, as
✍ Clotilde Mispelaere; Nicolas Roques πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 183 KB

Hemiaminals of trifluoroacetaldehyde are new trifluoromethylating agents. These reagents are synthesised from amines and gaseous trifluoroaeetaldehyde, tBuONa is able to deprotonate the hemiaminals to form trifluoromethyl anion equivalents CF3CH(O')NMe 2. The trifluoromethyl anion has been transferr