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ChemInform Abstract: HB9X×9 and H2B9X9 (X: Cl, Br, I): Neutral closo-Nonaboranes in the Novel Series BnHn+1, and BnHn+2 — Syntheses, ab initio Calculations, and Electronic Structures.

✍ Scribed by H. Binder; et al. et al.


Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
30
Category
Article
ISSN
0931-7597

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The closo-Cluster Triad: B9X9, [B9X9]· –
✍ H. Binder; R. Kellner; K. Vaas; M. Hein; F. Baumann; M. Wanner; R. Winter; W. Ka 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 396 KB

Halogenation of nido-B 10 H 14 with C 2 H 2 Cl 4 , C 2 Cl 6 , Br 2 , or I 2 , produces by cluster degradation the (2 n)-closoclusters B 9 X 9 (X = Cl, Br, I). The synthesis of salts of the perhalogenated radical anions of the type (2 n + 1)-closo-[B 9 X 9 ] ´± and of the corresponding dianions (2 n