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ChemInform Abstract: Halogen Exchange Reaction of Optically Pure Halotelluranes.

✍ Scribed by S. TAKAHASHI; J. ZHANG; S. SAITO; T. KOIZUMI


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis


1998 organo-tellurium compounds, isocyclic C derivatives organo-tellurium compounds, isocyclic C derivatives S 0144 16 -170 Halogen Exchange Reaction of Optically Pure Halotelluranes. -Optically pure chlorotelluranes [cf. (IV)] can be prepared by the reaction of the bromo borneol (I) with diarylditelluride followed by oxidative ring closure with tBuOCl. The halogen exchange with metal halides occurs with retention of configuration, suggesting an S N 1 pathway. -(TAKAHASHI, S.;


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