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ChemInform Abstract: Haloalkenes Activated by Geminal Groups in Reactions with N-Nucleophiles

✍ Scribed by A. YU. RULEV

Publisher: John Wiley and Sons
Year: 2010
Weight: 24 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199836339

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## Abstract Sodiumthiophenoxide and sodiumphenylselenide react with __N__‐benzyl‐ and __N__‐hexyl‐di‐__p__‐toluenesulfonamides (**1** and **2**) __via__ displacement at the C‐atom to afford the corresponding organosulfides and selenides in yields of 68–96%. In contrast, sodium cyanide converts disu