✦ LIBER ✦
ChemInform Abstract: Gold-Catalyzed Regioselective Hydration of Propargyl Acetates Assisted by a Neighboring Carbonyl Group: Access to α-Acyloxy Methyl Ketones and Synthesis of (.+-.)-Actinopolymorphol B.
✍ Scribed by Nayan Ghosh; Sanatan Nayak; Akhila K. Sahoo
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 59 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
In the presence of AuCl(PPh~3~)/AgSbF~6~, propargyl esters undergo simple, mild, and efficient hydration to give a wide range of α‐acyloxy methyl ketones.