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ChemInform Abstract: Gold-Catalyzed Cascade Friedel—Crafts/Furan-Yne Cyclization/Heteroenyne Metathesis for the Highly Efficient Construction of Phenanthrene Derivatives.

✍ Scribed by Yifeng Chen; Guijie Li; Yuanhong Liu


Publisher
John Wiley and Sons
Year
2011
Weight
35 KB
Volume
42
Category
Article
ISSN
0931-7597

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Gold-Catalyzed Cascade Friedel–Crafts/Fu
✍ Yifeng Chen; Guijie Li; Yuanhong Liu 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 247 KB

A rapid access to highly substituted phenanthrenyl ketones through gold-catalyzed cyclization of 1,6-diyn-4-en-3-ols with furans has been developed. Gold catalysts are effective to catalyze three cascade processes involving Friedel-Crafts/ furan-yne cyclization/heteroenyne metathesis through C À O b