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ChemInform Abstract: Gold-Catalyzed Activation of Epoxides: Application in the Synthesis of Bicyclic Ketals.

✍ Scribed by Rengarajan Balamurugan; Raveendra Babu Kothapalli; Ganesh Kumar Thota

Publisher
John Wiley and Sons
Year
2011
Weight
43 KB
Volume
42
Category
Article
ISSN
0931-7597

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Gold-Catalysed Activation of Epoxides: A
Gold-Catalysed Activation of Epoxides: Application in the Synthesis of Bicyclic Ketals
✍ Rengarajan Balamurugan; Raveendra Babu Kothapalli; Ganesh Kumar Thota πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 866 KB

## Abstract Gold‐catalysed generation of diol equivalents from epoxides and their intramolecular reaction with C≑C bonds to generate bicyclic ketals is presented. This reaction essentially involves the formation of an acetonide, which subsequently cyclises on the alkyne intramolecularly under gold