ChemInform Abstract: Glycosidation of 3,4,6-Tri-O-benzyl-2-ethenyl-D-glucal — A Route to 2-C-(β-Methyl)methylene Glycosides.
✍ Scribed by Ben-Ami Feit; Idil Kasuto Kelson; Anke Gerull; Sarah Abramson; Richard R. Schmidt
- Publisher
- John Wiley and Sons
- Year
- 2001
- Weight
- 33 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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Synthesis and Glycosidic Coupling Reaction of Substituted 2,6-Dioxabicyclo[3.1.1]heptanes: 1,3-Anhydro-2-azido-4,6-di-O-benzyl-2deoxy-β-D-mannopyranose. -The title sugar (VII) is synthesized via the key intermediate (VI) starting from glucopyranoside (I). Anhydrosugar (VII) is quite reactive: ring-