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ChemInform Abstract: Generation of Pyrrolo[2,1-a]isoquinoline Derivatives from N-Ylides: Synthetic Control and Structural Characterization.

✍ Scribed by Florea Dumitrascu; Mino R. Caira; Emilian Georgescu; Florentina Georgescu; Constantin Draghici; Marcel Mirel Popa

Publisher
John Wiley and Sons
Year
2012
Weight
26 KB
Volume
43
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

New pyrroloisoquinolines (III) are synthesized via 1,3‐dipolar cycloaddition between symmetrical acetylenic dipolarophiles (II) and isoquinolinium N‐ylides.

πŸ“œ SIMILAR VOLUMES

Generation of pyrrolo[2,1-a]isoquinoline
Generation of pyrrolo[2,1-a]isoquinoline derivatives from N-ylides: Synthetic control and structural characterization
✍ Florea Dumitrascu; Mino R. Caira; Emilian Georgescu; Florentina Georgescu; Const πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 211 KB

## Abstract New pyrrolo[2,1‐__a__]isoquinolines were obtained by two one‐pot procedures via 1,3‐dipolar cycloaddition between the isoquinolinium N‐ylides and symmetrical acetylenic dipolarophiles, avoiding the formation of dihydro intermediates. For structural comparison, the dihydro derivatives ob